Here are my settings for the Rocket League Tool in the Normal Freestyle Mode:
[Prediction]
Enable Prediction = true
Only In Goal = false
Intersection Point = true
Intersection Type = 1
Prediction Type = 1
Line Width = 10
Line Color A = 16
Line Color R = 60
Line Color G = 249
Line Color B = 155
Fade Out Line = true
Intersection Point Color A = 255
Intersection Point Color R = 255
Intersection Point Color G = 255
Intersection Point Color B = 255
Performance Lines = false
Iterations = 200
[Boost Timers]
Enable Boost Timers = true
Show Circles = false
Show Text = true
Text Lowering = false
Font Size Index = 0
[Boost Display]
Enable Boost Display = false
Show On Team = false
Show On Enemy = false
Show Bars = false
Show Numbers = false
Persistent Background = false
Background Type = 1
Background Color A = 150
Background Color R = 255
Background Color G = 255
Background Color B = 255
[Chat Messages]
Show Chat Messages = false
Show Enemy Messages = false
Show Team Messages = true
Team Colored Messages = false
Show Chat Window = false
Chat Window Auto-Scroll = true
Alpha = 220
[Wave Dash]
Enable Wave Dash = true
Continuous Mode = true
Wall Dashing = true
Legit Wall Dashing = true
Wave Dash Hotkey = 54
[Demolition Bot]
Enable Demolition Bot = true
Auto Boost = true
Always Boost = false
Demolition Bot Hotkey = 162
[Aerial Bot BETA]
Enable Aerial Bot = true
Aerial Mode = 4
Take-off Height = true
Starting Velocity = 1656.000000
Height = 576.270020
Enable Automation = true
Auto Boost = true
Always Boost = false
Auto Drive = true
Drive Backwards = true
Match Speed = false
Aim At Goal = true
Facing Goal = false
Ground Correction = 0.000000
Normal Aerial Correction = 85.000000
FreeStyle Aerial Correction = 135.800003
Aerial Bot Hotkey = 164
[Mini map]
Enable Minimap = false
Scale = 1.000000
Position X = 0
Position Y = 0
Show Boosts = false
Show Boost Timers = false
Show Chat Messages = false
Show Minimap Borders = true
[Misc]
Automatic Air Sensitivity = false
Hide Nameplates = false
Set FOV = true
Enable Prediction = true
Only In Goal = false
Intersection Point = true
Intersection Type = 1
Prediction Type = 1
Line Width = 10
Line Color A = 16
Line Color R = 60
Line Color G = 249
Line Color B = 155
Fade Out Line = true
Intersection Point Color A = 255
Intersection Point Color R = 255
Intersection Point Color G = 255
Intersection Point Color B = 255
Performance Lines = false
Iterations = 200
[Boost Timers]
Enable Boost Timers = true
Show Circles = false
Show Text = true
Text Lowering = false
Font Size Index = 0
[Boost Display]
Enable Boost Display = false
Show On Team = false
Show On Enemy = false
Show Bars = false
Show Numbers = false
Persistent Background = false
Background Type = 1
Background Color A = 150
Background Color R = 255
Background Color G = 255
Background Color B = 255
[Chat Messages]
Show Chat Messages = false
Show Enemy Messages = false
Show Team Messages = true
Team Colored Messages = false
Show Chat Window = false
Chat Window Auto-Scroll = true
Alpha = 220
[Wave Dash]
Enable Wave Dash = true
Continuous Mode = true
Wall Dashing = true
Legit Wall Dashing = true
Wave Dash Hotkey = 54
[Demolition Bot]
Enable Demolition Bot = true
Auto Boost = true
Always Boost = false
Demolition Bot Hotkey = 162
[Aerial Bot BETA]
Enable Aerial Bot = true
Aerial Mode = 4
Take-off Height = true
Starting Velocity = 1656.000000
Height = 576.270020
Enable Automation = true
Auto Boost = true
Always Boost = false
Auto Drive = true
Drive Backwards = true
Match Speed = false
Aim At Goal = true
Facing Goal = false
Ground Correction = 0.000000
Normal Aerial Correction = 85.000000
FreeStyle Aerial Correction = 135.800003
Aerial Bot Hotkey = 164
[Mini map]
Enable Minimap = false
Scale = 1.000000
Position X = 0
Position Y = 0
Show Boosts = false
Show Boost Timers = false
Show Chat Messages = false
Show Minimap Borders = true
[Misc]
Automatic Air Sensitivity = false
Hide Nameplates = false
Set FOV = true
FOV = 120.000000
If you want a feeling for this settings when to shoot here is a trainingsmap of mine: AFE1-558A-71BA-506A